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The Open Grid Forum (OGF) was created in 2006 from a merger of the Global Grid Forum (GGF) and the Enterprise Grid Alliance (EGA) to bring the entire grid community together. OGF will focus on accelerating the adoption of grid technology. Prior to the merger, the GGF had established a community of users, developers, and vendors leading the global standardization effort for grid computing. The GGF community included thousands of individuals in industry and research, representing more than 400 organizations in more than 50 countries. GGF s focus was primarily on the grid requirements of IT vendors, and the EGA s emphasis was on meeting the needs of enterprise users. The combined OGF will also focus on such things as how grids integrate with virtualization, SOAs (service-oriented architectures), and automated systems. OGF hopes to help overcome obstacles to adopting grid computing by including issues involving people, processes, and technology. Information about OGF s standards and activities can be found at http://www.ogf.org.

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Figure 11.22. Switching behavior of diffracted probe light with a lm of the shown azobenzene-containing side-chain liquid crystalline polymer at 143 1C exposed to writing beams (127 mW/cm2) for 62.5 ms. Source: Yamamoto et al., 2001. Reprinted with permission.

130 also be expressed as: vf=vg[k + a(T-TJ] (2.6.16)

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The principle of such writing beam controlled dynamic holographic gratings should be applicable to many azobenzene polymers or LCs. The grating formation time, related to the trans cis photoisomerization, should always be fast, but the grating erasure time, determined by the thermal relaxation of cisazobenzene, may be much longer depending on the material and experimental conditions. The interest of Ikeda s work is the use of the photoisomerizationinduced phase transition (termed photochemical phase transition ) in azobenzene SCLCPs to amplify the difference in refractive index that is required for highly ef cient diffraction. Nevertheless, the polymer needs to be held at temperatures close to Tni to ensure fast photochemical phase transition and thermal relaxation of cis-azobenzene, which determine the diffraction switchingon and switching-off times.

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where vg is the volume per molecule at the glass transition temperature, Tg, a is the thermal expansion coefficient of the polymer, and A is a : non-dimensional constant. The ion transport in the polymer is conditioned by the formation of sufficiently large voids in the polymeric skeleton. The probability of this process, p, decreases exponentially with the total-to-free volume ratio, v/v{: p=exp(-v/vf) Equations (2.6.16) and (2.6.17) can be rearranged to the form: p =exp[-B/(r-r0)] (2.6.18) (2.6.17)

11.5.2.1. Materials Design and Switching Mechanism. The dynamic holographic grating recorded with azobenzene SCLCPs is erased once the writing beams are turned off. It is of interest to develop materials with which one can record a stable diffraction grating that, after formation, can be repeatedly

where B and To are constants (To is usually 20-50 C lower than 7^). Using Eq. (2.6.18) the temperature dependence of various transport properties of polymers, such as diffusion coefficient D, ionic conductivity a and fluidity (reciprocal viscosity) 1/rj are described, since all these quantities are proportional to p. Except for fluidity, the proportionality constant (pre-exponential factor) also depends, however, on temperature, D~Tm; o~T-m'p; 1/rj-p (2.6.19)

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switched using light. Using photopolymerization-induced phase segregation, we demonstrated that this could be done with an azobenzene polymer stabilized nematic LC (Tong et al., 2005b). The diffraction ef ciency of probe light through such a grating can be switched between high and low values with UV and visible light as a result of the photoisomerization of the azobenzene chromophore. In addition, since the grating is made with LC-based materials, the switching of diffraction ef ciency can also be achieved by an electric eld that controls the LC orientation. Therefore, the grating displays a dual-mode (optical and electrical) tunability. The design principle for the material leading to the grating formation is schematized in Fig. 11.23. An azobenzene monomer is dissolved in a nematic LC, together with a photoinitiator (not shown). The homogeneous mixture is then exposed to light through a grating photomask for photopolymerization. Similar to the grating formation using PDLCs (Sutherland et al., 1994), as polymerization takes place only in irradiated areas, formation of polymer results in diffusion of the monomer from nonirradiated areas into the irradiated areas. This process expels the LC from irradiated areas as more polymers are formed and solidi ed, the consequence of which should be the segregation of the polymer from the LC host leading to the formation of a permanent volume grating. However, it is likely that a small amount of the azobenzene monomer would remain dissolved in the

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