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The trans cis photoisomerization of this azobenzene monomer in THF is almost 100%, and because of the LC-enhanced solubility, as much as 30% of the monomer can readily be dissolved in nematic LCs The nematic LC used to test the design was BL006 (Tni = 1151C), characteristics of which are suitable to the tunable grating: an ordinary refractive index no = 153, a large birefringence Dn = 0286 (589 nm, 201C), and a positive dielectric anisotropy De = 173 The photoinitiator used was Irgacure 784 that can initiate polymerization upon visible light absorption at lW450 nm, which is important because the long-wavelength initiation reduces the interference by the absorption of the LC host and the azobenzene monomer (lmax = 354 nm in THF) This materials combination indeed allows for the preparation of optically and electrically switchable gratings.

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Swelling of the polymer by the solvent is described by the volume fraction of the pure polymer in the gel (Vp) The diffusion coefficient of ions in the gel (Dp) is related to that in the pure solvent (Do) according to the equation: Dp = A) exp [-kVp/(l - Vp)] (2621).

installable unit (IU) of software. More information can be found in Appendix B and at http://www.oasis-open.org.

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Using the example of a grating formed with a mixture containing 15% azobenzene monomer and 2% photoinitiator, the origin of the dual-mode switching of diffraction ef ciency is explained with Fig 1124 The grating was obtained by applying a beam of visible light (540 nm, B28 mW/cm2) through the photomask (40-mm stripes) placed on one side of an ITO-coated parallely rubbed cell (10-mm gap) lled with the LC/monomer/ initiator mixture, the mask stripes being aligned parallely to the rubbing direction Using a microscope hot stage, the photopolymerization proceeded at 1251C (in the isotropic phase of BL006) for 1 h before being cooled to room temperature under visible irradiation; after removal of the mask, a ood irradiation was applied to the whole sample to complete polymerization of the remaining monomer Figure 11.

where k is a constant. Another example of ion conducting polymer/ion/solvent systems are polyelectrolytes based on ion-exchange polymers, also called ionomers. The ionic conductivity of ion-exchange polymers is usually very low in the dry state, but increases abruptly by orders of magnitude upon addition of a

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24a shows the POM of the cell placed with the rubbing direction parallel to one of crossed polarizers (along the x-axis) The grating arising from the polymerization-induced segregation is visible Polymer strips are found in irradiated areas and well separated from the LC concentrated in nonirradiated areas The orientation of LC molecules along the rubbing direction in the LC regions is revealed by the extinction in these areas As illustrated in the schematics under the.

132 small amount of a liquid solvent (several molecules per one immobilized ionic group). The most important representatives of ionomers are sulphonated fluoropolymers, such as Nafion:

The Storage Networking Industry Association (SNIA) is a not-for-profit global organization made up of more than 460 member companies and close to 7,000 active individuals spanning virtually the entire storage industry. The association s goal is to advance the adoption of storage networks as complete and trusted solutions. SNIA is active in delivering standards, education, and services. One of its main accomplishments is the ongoing development and adoption of the Storage Management Initiative Specification (SMI-S), which defines a standard for interoperability in managing storage networking resources. More information can be found in Appendix B and at http://www.snia.org.

trans-azo cis-azo np ne np n*

where m is about 13 This material was first synthesized in the middle 1960s by EI Du Pont de Nemours and Co, and was soon recognized as an outstanding ion conductor for laboratory as well as for industrial electrochemistry The perfluorinated polymeric backbone is responsible for the good chemical and thermal stability of the polymer Nafion membrane swollen with an electrolyte solution shows high cation conductivity, whereas the transport of anions is almost entirely suppressed This so-called permselectivity (cf Section 621) is a characteristic advantage of Nafion in comparison with classical ion-exchange polymers, in which the selective ion transport is usually not so pronounced Thanks to its high stability and permselectivity, Nafion has been used as a Na+ conductor in membrane electrolysis of brine in the chlor-alkali industry.

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