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Fig. 2.20 The Gierke model of a cluster network in Nafion. Dimensions are expressed in nm. The shaded area is the double layer region, containing the immobilized SO3 groups with corresponding number of counterions M + . Anions are expelled from this region electrostatically

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In this case, the probe light sees essentially no and np in the alternating regions, and the sharp decrease in index modulation should result in a drop of the diffraction ef ciency The electrical switching of index modulation should be reversible, since the initial planer orientation of LC can be recovered when the electric eld is turned off More interestingly, the index modulation can also be reversibly changed by light using two different wavelengths Illuminating the grating with a UV light (360 nm), azobenzene groups on the polymer remaining in the LC regions undergo the trans cis photoisomerization that can induce the photochemical nematic isotropic phase transition at room temperature This can be observed in Fig 1124d where the LC stripes appear signi cantly darker because of disordered LC molecules.

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134 'trapped' inside the clusters owing to the high electrostatic barrier in the hydrophobic channel where the shielding effect is suppressed. This makes it clear why the channels are preferentially conductive for cations, i.e. the polymer membrane (despite the presence of free anions) is not anionconducting. Diffusion of cations in a Nafion membrane can formally be treated as in other polymers swollen with an electrolyte solution (Eq. (2.6.21). Particularly illustrative here is the percolation theory, since the conductive sites can easily be identified with the electrolyte clusters, dispersed in the nonconductive environment of hydrophobic fluorocarbon chains (cf. Eq. (2.6.20)). The experimental diffusion coefficients of cations in a Nafion membrane are typically 2-4 orders of magnitude lower than in aqueous solution.

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When this happens, the probe light experiences mainly the average refractive index of the LC, n* = (2no+ne)/3, which should be close to np, leading to a drop of the diffraction ef ciency While illuminating the grating with a visible light (440 nm), the back cis trans photoisomerization of azobenzene occurs that allows the initial surface-induced LC orientation to be recovered As already mentioned, the polymer and LC strips forming the grating are actually polymer- and LC-rich regions Figure 1125 shows a magni ed POM image of the grating, where azobenzene polymers remained in the LC regions are clearly noticeable On the basis of the morphology of the azobenzene polymerstabilized LCs revealed on POM (Leclair et al, 2003), the estimated amount of polymer in the LC regions is B3%.

References Conway, B. E., Proton solvation and proton transfer in solution, MAE, 3, 43 (1964). Dekker, A. J., Solid State Physics, Prentice-Hall, Englewood Cliffs, 1957. Eisenberg, A. E., and H. L. Yeager (Eds), Perfluorinated Ionomer Membranes, ACS Symposium Series 180, ACS, Washington, 1982. Glasstone, S., H. Eyring, and K. J. Laidler, Theory of Rate Processes, McGrawHill, New York, 1942. Hertz, H. G., Self-diffusion in solids, Ber. Bunsenges., 75, 183 (1971). Hladik, J. (Ed.), Physics of Electrolytes, Academic Press, New York, a multivolume series, published since 1972. Huggins, R. A., Ionically conducting solid state membranes, AE, 10, 323 (1977). Inman, D., and D. C. Lovering (Eds), Ionic Liquids, Plenum Press, New York, 1981. Kittel, C , see page 104. Laity, R. W., Electrochemistry of fused salts, /. Chem. Educ, 39, 67 (1962).

Linford, R. G., Electrochemical Science and Technology of Polymers, Vol. 1 & 2,

Likewise, the polymer regions also con ne LC molecules whose switching at the eld-on state is responsible for the darker appearance of the polymer strips in Fig 1124c Nevertheless, as shown in Section 11522, experimental data of both electrical and optical switching of the diffraction grating corroborates quite well the analysis of index modulation changes without taking into account the remaining polymer or LC, suggesting that the residual amount of polymer or LC in the LC or polymer regions, respectively, is minor and does not determine the switching behavior of the grating 11522 Optical and Electrical Switching Behaviors The grating in Fig 1124 was used to investigate the switching behavior of diffraction ef ciency using light at two wavelengths (UV and visible) as well as an electric eld The setup was the same as described in Section 114.

This chapter focuses on assessing your hardware requirements. It poses questions to ask as you make decisions on whether and where blade systems are right for you. It also offers tips for your consideration during your product selection and implementation processes.

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