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Photo induced phase transition of side chain liquid crystalline copolymers with photochromic group Eur Polym J 31(1):23 28 He J A, et al 2000a Photochemical behavior and formation of surface relief grating on self assembled polyion/dye composite lm J Phys Chem B 104(45):10513 10521 He J A, et al 2000b Surface relief gratings from electrostatically layered azo dye lms Appl Phys Lett 76(22):3233 3235 Higuchi M, Minoura N, Kinoshita T 1994 Photocontrol of micellar structure of an azobenzene containing amphiphilic sequential polypeptide Chem Lett (2):227 230 Higuchi M, Minoura N, Kinoshita T 1995a Photoinduced structural and functional changes of an azobenzene containing amphiphilic sequential polypeptide Macromole cules 28(14):4981 4985 Higuchi M, Minoura N, Kinoshita T 1995b Photo responsive behavior of a monolayer composed of an azobenzene containing polypeptide in the main chain Colloid Polym Sci 273(11):1022 1027..

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The steady-state distribution of the concentration of the diffusing substance at the phase boundary is termed the Nernst layer.t For the material flux (cf. Eq. 2.5.18) we have Jy=^r (c - c*) = K(C - c*) (2.7.2)

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Hildebrandt R, et al. 1998. Time resolved investigation of photoinduced birefringence in azobenzene side chain polyester lms. Phys Rev Lett 81:5548 5551. Ho C H, Yang K N, Lee S N. 2001. Mechanistic study of trans cis isomerization of the substituted azobenzene moiety bound on a liquid crystalline polymer. J Polym Sci, Part A 39(13):2296 2307. Ho MS, et al. 1996. Synthesis and optical properties of poly{(4 nitrophenyl) [3 [N [2 (methacryloyloxy)ethyl]carbazolyl]]diazene}. Macromolecules 29(13):4613 4618. Hohsaka T, Kawashima K, Sisido M. 1994. Photoswitching of Nad+ mediated enzyme reaction through photoreversible antigen antibody reaction. J Am Chem Soc 116(1):413 414. Holland NB, et al. 2003. Single molecule force spectroscopy of azobenzene polymers: switching elasticity of single photochromic macromolecules. Macromolecules 36(6):2015 2023. Holme NCR, Ramanujam PS, Hvilsted S. 1996. 10,000 optical write, read, and erase cycles in an azobenzene sidechain liquid crystalline polyester. Opt Lett 21(12):902 904. Hong J D, Jung B D, Kim CH, Kim K. 2000. Effects of spacer chain lengths on layered nanostructures assembled with main chain azobenzene ionenes and polyelectrolytes. Macromolecules 33(21):7905 7911. Hore DK, Natansohn A, Rochon PL. 2002. Optical anisotropy as a probe of structural order by stokes polarimetry. J Phys Chem B 106(35):9004 9012. Hore DK, Natansohn AL, Rochon PL. 2003. Anomalous cis isomer orientation in a liquid crystalline azo polymer on irradiation with linearly polarized light. J Phys Chem B 107(10):2197 2204. Houben JL, et al. 1983. Azobenzene containing poly(L glutamates) conformation in solution. Int J Biol Macromol 5(2):94 100. photochromism and

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where D is the diffusion coefficient and K = D/6 is the mass transfer coefficient (this term is employed in chemical and electrochemical engineering). 2.7.2 The theory of convective diffusion The material flux during convective diffusion in an indifferent electrolyte (grad 0 0) can be described by a relationship obtained by combination of Eqs (2.3.18) and (2.3.23): J = Jdif + Jconv = -D grad c + cv (2.7.3) where Jdif is the diffusion and Jconv the convection material flux. Equation (2.2.10) for ip = c and the incompressibility condition divv = 0 (2.7.4) yield -^ = DV2c - v grad c or, for the steady state, DV2c - v grad c = 0 In Cartesian coordinates, this equation becomes (d2c d2c d2c\ ( Be dc y \dx dy dz I \ dx dy (2.7.6) 3c\ dz) (2.7.5)

Hugel T, et al. 2002. Single molecule optomechanical cycle. Science 296(5570):1103 1106. Hvilsted S, Andruzzi F, Kulinna C, Siesler HW, Ramanujam PS. 1995. Novel side chain liquid crystalline polyester architecture for reversible optical storage. Macromolecules 28(7):2172 2183. Ichimura K. 2000. Photoalignment of liquid crystal systems. Chem Rev 100(5):1847 1873. Ichimura K, Han M. 2000. Molecular reorientation induced by sunshine suggesting the generation of absolute chirality. Chem Lett 29(3):286 287. Ichimura K, Hayashi Y, Akiyama H, Ikeda T, Ishizuki N. 1993. Photo optical liquid crystal cells driven by molecular rotors. Appl Phys Lett 63(4):449 451. Ichimura K, Momose M, Kudo K, Akiyama H, Ishizuki N. 1996. Surface assisted formation of anisotropic dye molecular lms. Thin Solid Films 284 285:557 560. Ichimura K, Oh S K, Nakagawa M. 2000. Light driven motion of liquids on a photo responsive surface. Science 288(5471):1624 1626. Iftime G, Labarthet FL, Natansohn A, Rochon P, Murti K. 2002. Main chain containing azo tetraphenyldiaminobiphenyl photorefractive polymers. Macromolecules 14(1):168 174. Ikeda T, Tsutsumi O. 1995. Optical switching and image storage by means of azobenzene liquid crystal lms. Science 268(5219):1873 1875. Ikeda T, Horiuchi S, Karanjit DB, Kurihara S, Tazuke S. 1990. Photochemically induced isothermal phase transition in polymer liquid crystals with mesogenic phenyl benzoate

f Nernst studied the theory of heterogeneous reactions around the year 1900 and assumed that the flow of a liquid along a phase boundary with a solid phase involves formation of an immobile liquid layer at this surface. A steady-state concentration gradient is then formed within this layer as a result of diffusion in the limited space (see Eq. 2.5.18). In fact, the diffusion process has the character of convective diffusion everywhere as a result of the velocity distribution in the hydrodynamic layer.

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