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LC media, implying that the microphase domains can be controlled by manipulating LC alignment under SMCM. The present rubbing results technologically implicated that other LC manipulating ways can be used to regulate the azo LCBC lms.

(where the symbol w indicates that the substances are present in aqueous solution). It is further assumed that the HC1 activity in cell (3.1.40) equals unity. The quantity HU")

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In the mechanical rubbing process to control LC alignment, dust or static electricity might be produced, which could induce defects in the macroscopic array of microphase-separated nanostructures in azo LCBC lms, and this method can only be applied for a at surface Therefore, noncontact methods, such as photocontrol approaches, have been explored (Yu et al, 2006a) Light is one of the most convenient and cheap energy sources, whose intensity, wavelength, polarization direction as well as interference patterns can be manipulated simply More perfect and simpler fabrication of microphase-separated nanostructures in azo LCBC lms is expected by photocontrol Upon irradiation with linearly polarized light, azo chromophores are known to undergo photoinduced alignment with transition moments almost perpendicular to the polarization direction by repetition of trans cis trans isomerization cycles (eg, Viswanathan et al, 1999).

is the standard EMF of the cell. In the present case where the electrode on the left in the graphical scheme is the standard hydrogen electrode, E is termed the standard electrode potential. Standard electrode potentials are denoted as E with a subscript in which the initial substances in the half-cell reaction are given first, separated from the products by a slanted line; e.g. the standard potential of the silver-silver chloride electrode is designated as Agci/Ag,ci-- For typographical reasons, however, it is prefable to include the reactants in parentheses as follows: Agc,/Ag,cr - (AgCl + e = Ag + Cl") - AgC,/Ag,cr (3.1.55)

Such ordering can be transferred directly to other photoinert mesogens by MCM coinciding with the ordered azo moieties By incorporating the photoinduced alignment of azo into LCBC with SMCM, the molecular ordering of the azo can be transferred to a supramolecular level Therefore, well-ordered nanostructures of the azo LCBC lms might be obtained by photocontrol (Ikeda and Tsutsumi, 1995) As shown in Fig 1214, a linearly polarized laser beam at 488 nm was used to control PEO nanocylinders self-assembled in an amphiphilic azo LCBC of wellde ned structure To enhance the absorption at 488 nm, a pseudostilbene-type azo with a cyano group as an electron acceptor substituent was used in preparation of the azo LCBC Upon annealing without photoirradiation, hexagonal packing of the PEO cylinders perpendicular to the glass substrates was obtained, because of the out-of-plane orientation of the azo mesogens, which is similar to that in Fig 12.

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It follows directly from the definition of the standard potential that, for the hydrogen electrode,

10 The photoinduced alignment of azo moieties was carried out at room temperature, and then the anisotropic azo LCBC lms were thermally annealed at a temperature just lower than the phase transition temperature of smectic LC-toisotropic phase Perfect array of PEO nanocylinders aligned perpendicularly to the polarization direction of the laser beam because of SMCM was achieved Recently, Seki and coworkers reported a PEO nanocylinder control method by a periodic change in lm thickness induced by mass transfer to form holographic gratings (Morikawa et al, 2006) In their preparation, the lm thickness was strictly modulated, and the azo BC was mixed with a low molecular-weight LC (5CB) to photoinduce a large mass transfer, and 5CB was eliminated after grating formation To simplify the process, they adopted a polarized beam to control the nanocylinders in PS-based azo LCBC lms (Morikawa et al, 2007).

(3.1.56)

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t It follows from Section 1.3.1 that the expression for the chemical potential must contain the pressure referred to the standard pressure; thus p = 1 corresponds to standard pressure, 102 kPa. The activities in these expressions are also dimensionless and correspond to units of moles per cubic decimetre because of the choice of the standard state.