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deformation before the yielding or failure, but the strain generally is very small (a few percent), and the stress is high. In recent years, we have demonstrated a new type of azobenzene polymers, namely, azobenzene thermoplastic elastomers (ATEs) (Cui et al., 2004; Zhao et al., 2003; Bai and Zhao, 2002; Zhao et al., 2002; Bai and Zhao, 2001). As a unique feature, thin lms of variable thickness can easily be prepared through their solution casting, and they are capable of undergoing large and reversible deformation at room temperature. Studies by the author s group found that they are interesting photosensitive materials for mechanically tunable diffraction gratings.

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ATEs differ from conventional elastomers (Camacho-Lopez et al, 2004) in that their network structure and elastic deformation under stress are supported by physical cross-links rather than chemical (covalent) cross-linking This is why they can be dissolved in a solvent or be melted at elevated temperatures for processing like a thermoplastic polymer One important category of thermoplastic elastomers is the ABA-type triblock copolymer, with the central B block being a room temperature elastomer (amorphous, low Tg) and the two end blocks being a high Tg (or high Tm) polymer Basically, at appropriate copolymer compositions, the microphase separation because of the immiscibility of the two constituent polymers (A and B blocks) can lead to the formation of rigid microdomains of A that, by interconnecting the rubbery chains of B, act as the physical cross-links supporting the elastic deformation under stress.

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HPC implementations distribute a single computational task across multiple cluster nodes for increased performance. HPC, as mentioned briefly earlier, came about when researchers required more processing power but could not afford the very expensive mainframes. After adding custom-built resource managers and schedulers, they were able to leverage their commodity PCs (which were sitting idle and/or underutilized) by interconnecting them in a

(d2c t = 0, t>0, t>0,

2 3c c = c c=0 c = c (2.5.19)

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11 Oct 2014 ... ZXing ("Zebra Crossing") is the popular API for QR code processing in Java . Its library has multiple components and we will be using the 'core' for QR code creation in our Java example. Following code is example to create a QR code image and read information from a QR code image.

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The author s group developed two methods for the synthesis of azobenzene thermoplastic elastomers (ATE), as depicted in Fig 113 The rst method (Fig 113a) consists in grafting an azobenzene side-chain liquid crystalline polymer (azo-SCLCP) onto a styrene butadiene styrene (SBS) triblock copolymer, which is a commercially available thermoplastic elastomer [with B30% polystyrene (PS)] By simply polymerizing an azobenzene acrylate (or methacrylate) monomer in a toluene solution with dissolved SBS, using benzoyl peroxide as the free radical initiator, the grafting can be achieved (Bai and Zhao, 2002, 2001) The reaction mechanisms may involve both a radical transfer to the methylene group of the polybutadiene (PB) block that initiates the polymerization of the azobenzene monomer and a direct reaction of propagating radicals of azo-SCLCP with the double bonds of PB Depending on the experimental conditions and the monomer used, the amount of azo-SCLCP grafts varies from B8% to 22%.

makeshift distributed fashion. This configuration allowed the computational workload to be subdivided across the collection of systems. HPC clusters (HPCCs) are now optimized for high-speed communications between the cluster nodes when interprocessor communications are required during computations. The compute capabilities of HPCCs coupled with high-speed networking and low-latency implementations such as RDMA (as described in 6, Networking and Related Technologies ) have been shown to meet and even exceed the speeds of supercomputers. Most applications designed to exploit HPCCs through parallelism are custom and computationally intensive. These applications often can be run on symmetric multiprocessing systems as well. Industries such as EDA (electronic design automation), CAE (computer-aided engineering), and oil and gas commonly require applications of this sort. Blade solutions can be extremely effective for HPCCs because of the support for multiple processors on each blade, as well as the high-speed interconnect (GbE, 10GbE, and InfiniBand) networking technologies available. As Figure 9.3 shows, multiple types of HPCC environments can be accommodated easily with a blade solution. With the switch modules located within the blade chassis, or rack, distances and hops through a network are minimized, reducing latency. Many blade solutions come preconfigured for HPCC environments.

where r0 is the radius of the sphere. The concentration gradient for r = r0 is given by the equation (dc\ c c =-7=^+(2.5.20)

Figure 114 shows the photos of solution-cast lms of the starting SBS and an ATE sample containing 8% of azo-SCLCP The lm of ATE is transparent as SBS After drying, the ATE lm can be peeled off from the glass slide and repeatedly stretched to a strain as high as 500% The elasticity of ATE comes from the SBS, in which the rubbery PB chains are interconnected by the glassy PS cylindrical microdomains acting as the physical cross-links In ATE, the grafts of azo-SCLCP are embedded in the rubbery PB matrix and, in some samples, may form their own microdomains A controlled free radical polymerization technique was also used, namely, atom transfer radical polymerization (ATRP), to synthesize ATE on the basis of ABA triblock copolymers (Fig 113b) (Cui et al, 2004).

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