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Fig. 3.3 Fermi level of two metals in contact: (A) situation before the contact when both phases have different Fermi levels, e (ar) and e (/3); (B) after coming into contact both the phases assume the same Fermi level, eF

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For instance, a thin layer of an azobenzene polymer could be cast on the surface of an elastomer containing no azobenzene; if SRG can be inscribed on surface of the azobenzene polymer, mechanical deformation of the supporting elastomer may control the SRG deformation and thus change its diffraction properties The mechanical tunability of gratings on ATE lms is also worth exploitation for possible applications One possibility would be to incorporate this sort of grating into a structure (architecture, instruments) in such a way that a small deformation of the structure can induce a change in grating period and thus be detected by a changing diffraction angle In principle, elastomers can undergo larger thermal expansion because of polymer chain exibility Such a grating might be used as a sensor for the detection of abrupt temperature change, since a large thermal expansion can cause changes in index modulation and grating period.

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As poet and philosopher George Santayana put it, Those who cannot remember the past are condemned to repeat it. It is helpful, therefore, to start with a brief history of the eras of computing mainframes, PCs and workstations, client/server, the Internet, and now the consolidation era. We will then look at the promise of next-generation data centers, and whether they will deliver true utility computing enabled by blades and virtualization technologies.

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the just half-filled level. For semiconductors, the Fermi level lies in the forbidden band between the conductance and valence bands depending on the presence of donor and acceptor levels. At the contact of two electronic conductors (metals or semiconductors see Fig. 3.3), equilibrium is attained when the Fermi levels (and thus the electrochemical potentials of the electrons) are identical in both phases. The chemical potentials of electrons in metals and semiconductors are constant, as the number of electrons is practically constant (the charge of the phase is the result of a negligible excess of electrons or holes, which is incomparably smaller than the total number of electrons present in the phase). The values of chemical potentials of electrons in various substances are of course different and thus the Galvani potential differences between various metals and semiconductors in contact are non-zero, which follows from Eq. (3.1.6). According to Eq. (3.1.2) the electrochemical potential of an electron in

jUe(<*) = jUe(tf) F(j)(a) (3.1.11)

In the case of electrically switchable gratings, LCs remain the material of choice because of the ease of molecular reorientation under the effect of a voltage The photoisomerization of azobenzene should play the role of trigger for the grating formation Self-assembled LC gels combine the property of electric eld orientation of LCs and the possibility of a structural rearrangement induced by the photoisomerization of the azobenzene gelator Even though the grating obtained from the cholesteric LC gel as described in Section 114 falls short for practical applications, the interest of exploiting self-assembled LC gels is clear, since this approach may be generalized for many systems made from designed gelators and various types of LCs The key to the grating formation process in self-assembled LC gels is the dissolution of the physical network in the LC host in irradiated areas.

18

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This may be enhanced by using azobenzene gelators whose cis form has a signi cantly higher polarity than the trans form, which increases the surface tension of the brous aggregates It also helps if the gelator could form very thin nano brous aggregates giving rise to a large speci c surface and thus a signi cant number of gelator molecules on the surface undergoing the trans cis photoisomerization Finally, further research effort is worth being made on materials for recording optically switchable diffraction gratings Optical control of optical properties, such as the diffraction, is not only academic curiosity but required for the.

If an electronic conductor is in contact with an electrolyte solution containing the components of a simple redox system consisting of the ionic species Ox (charge numbers zOx) and Red (charge number zRed) Ox + ze = Red (3.1.13) where z = zOx zRed (Fig. 3.4) then the relationship for the energy of the Fermi level in the solution eF(J3) can be formulated as follows. The occupied

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