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Functional block copolymers (BCs) are among novel types of macromolecules of industrial and academic interest because they provide opportunities to study the nanostructure formation and control under the in uence of more than one driving force, for example, the effect of microphase-separated nanostructures on functionality, and vice versa, the in uence of a speci c functionality on the formation of diverse nanostructures. Introducing an azo block as one of the constituent segments into the functional BCs, azo BCs can be easily obtained, which are expected to bring the well-characterized photoisomerization of the azo moiety into the microphase separation of BCs (e.g., Natansohn and Rochon, 2002; Seki, 2004). Moreover, if the azo block can form mesogenic phases, the regular periodicity of liquid crystalline (LC) ordering in uences the microphase-separated nanostructures, making it possible to self-assemble into periodic nanostructures on the macroscopic scale. In bulk lms of liquid crystalline block copolymers (LCBCs), the interplay between the microphase separation and the elastic deformation of LC ordering, known as supramolecular cooperative motion (SMCM), enables one to form more hierarchical structures with photoresponsive properties, which offer novel opportunities to control supramolecular selfassembled nanostructures (e.g., Yu et al., 2006a,b). Combining the excellent properties of azo polymers with microphase separation, azo BCs may nd diverse applications in advanced technology as well as newly promising nanotechnology. Because of the incompatibility of the azo block and other non-azo segments in bulk lms, the azo block gives rise to a rich variety of nanostructures. For instance, AB-type azo diblock copolymers may form separated phases (e.g., spheres,

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EAN - 128 (also known as: EAN - 128 , UCC- 128 , USS- 128 , UCC. EAN - 128 , and GTIN- 128 ) is developed to provide a worldwide format and standard for exchanging common data between companies. It is a variable-length linear barcode with high density.

The chemical potential of insoluble salt BA, fiBA, depends on its solubility product according to the relationship (cf. Section 1.5.1) &A = RT In PBA + MB+(y) + ^ - ( y ) so that Eq. (3.1.24) can be rearranged to give A"<t> = & & j y RT + In PBA - I aA-(y) In P BA In

Although power is an important factor, cooling tends to be the more common barrier listed by users in moving to a blade architecture. Therefore, we will focus on the various approaches, features, and tips for addressing cooling concerns, and will address power issues as they apply.

(3.1.25)

Smart Light Responsive Materials. Edited by Yue Zhao and Tomiki Ikeda Copyright r 2009 John Wiley & Sons, Inc.

\naA(y)

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Every server, whether tower, rack, or blade, generates heat. More servers generate more heat; fewer servers generate less heat. Consolidation of physical servers reduces the number of physical servers within the data center, which not only reduces the amount of heat generated, and thus the amount of cooling required, but also reduces the floor space required. Consolidating servers can be accomplished in multiple ways. First, for applications that play nicely together on a single operating system, it is possible to consolidate applications that previously have been spread across physical servers, by stacking them together on a single server. Server virtualization goes the next step by consolidating entire servers as virtual servers onto a single physical server. When consolidation and virtualization are implemented together with blades, the reduction in cooling and floor-space requirements can and should be highly beneficial and carefully considered in your data-center planning.

Block "A" (azo)

(3.1.26)

Block "B"

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From the outset, the high density of blade systems created a higher heat output per footprint than rack servers. In addition, as blade systems began to use higher-speed processor chips, the heat (and, thus, the cooling issues) intensified. Fortunately, during this same evolution, a number of other features were introduced at the chip level, the blade and chassis level, and even in related software.

Two solid electrolytes in contact with a common ion show behaviour analogous to two metals in contact.

Figure 12.1. Microphase separation in bulk lms of azo diblock copolymers with well-de ned structures. The light domains represent the azo segment A, whereas the dark parts are formed from another non-azo block B.

153 As pointed out by J. W. Gibbs in 1875, thermodynamic procedures cannot be used to measure Galvani potential differences between chemically different phases (see page 144). Thus Eqs (3.1.12), (3.1.17), (3.1.18), (3.21) to (3.1.24) and (3.1.26) cannot be directly verified by measuring equilibrium quantities. However, their derivation was not pointless, because, as will be shown in Section 3.2, they have a form analogous to the relationships for equilibrium electrode potentials, consisting of several Galvani potential differences. Equilibrium measurements can be used only to determine the Galvani potential differences between chemically identical phases, which is strictly possible only for two identical electronic conductors. Then A 0=^ (3.1.27)

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cylinders), lamellae, or continuous phases by gradually increasing the azo content in the BC composition, which makes their properties different from those of azo polymer blends or azo random copolymers. Figure 12.1 shows a schematic representation of the microphase separation of an AB-type diblock copolymer, in which block A is an azo polymer segment and block B represents a non-azo polymer. Even if the azo block constituent is the minority phase in BC lms on the nanoscale (o100 nm), it retains its photochemical sensitivity and can be photomanipulated into an ordered state with the transition moments of azo moieties almost perpendicular to the polarization direction of the actinic light according to the Weigert effect (e.g., Ikeda, 2003a), which improves its optical performance by eliminating the scattering of visible light. Azo groups in the majority phase show a behavior similar to that of azo homopolymers. Additional performances such as hydrophilicity (e.g., Yu et al., 2006a,b), crystallization, optical transparency (e.g., Yu et al., 2007a,b), thermoplasticity (Cui et al., 2004), ionization (Qi et al., 2005), and water solubility (Ravi et al., 2005) can be acquired by special molecular design of the non-azo block B. Since the fascinating azo BC offers an effective and convenient method to design advanced materials with more than two functionalities, it has become one of the emerging topics in novel azo materials. This chapter tries to introduce this eld from the preparation method and basic properties to the control of their

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