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Many aspects of power and cooling challenges have been and continue to be addressed by the various chip and blade vendors, helping to mitigate the barriers to blade adoption. However, these features and improvements can only go so far. The final and critical element in dealing with power and cooling is in data-center facilities planning and management. This section discusses these planning issues and offers tips to help you prepare your data center for highdensity computing.

(5.6.4)

Scheme 12.4 Schematic illustration of the synthesis of well-de ned azo BCs by a polymer analog reaction.

where c = cA + cAH+- If aH3O+ K' (5.6.5) assumes the form /

Upon supramolecular self-assembly, low molecular-weight additives can be used to adjust the properties of BC bulk lms by hydrogen bonds. Ikkala and coworkers rst introduced this concept in PS-b-poly(4-vinylpyridine) (P4VP) stoichiometrically complexed with pentadecylphenol molecules to form the supramolecules by hydrogen bonding (Makinen et al., 2000). The advantages of this method are as follows: 1. Selective hydrogen bonding between one of the blocks (P4VP) of BCs and the additive 2. Obvious microphase separation in bulk lms 3. Easy extraction of the additive by selective solvents

The concept of alternating hot aisles and cold aisles was created by Robert Sullivan (now of the Uptime Institute) in 1992 while he was at IBM. The idea is simple: Instead of having all the data-center equipment facing the same direction, so that heat comes out of the back of each row and into the front of the next row, equipment is installed in rows that face each other. Cold aisles, the aisles in which the equipment racks are facing each other, are created with vented floor tiles that allow cool air to come up from under the raised floor, so the cool air goes into the front of the racks and out the back into the hot aisles. Hot aisles are those in the back of the racks, and the floor

(5.6.6)

Scheme 12.5 Synthesis of azo BCs by a polymer analog reaction. Source: Reproduced with modi cations from Mao et al., 1997.

with an overall reaction order of 2. The deposition of a metal from a complex also involves equilibria in solution between the free metal ions, the complexed ions and the complexing agent. The formation of the complex MXZ+ from the metal ion Mz+ and complexing agent X is characterized by the consecutive stability constants (Section 1.4.3)

tiles are not vented. This separates the cool air source in front from the hot air that is sent out into the room. Hot-aisle tiles are not vented, because vented tiles in the hot aisle would mix hot and cold air. In order for the cooling units to be at their most efficient, you want the air that returns to the cooling units to be hot.

Scheme 12.6 An amorphous azo BC prepared by PACR. Source: Reproduced with modi cations from Wang et al., 2007.

so that the solution contains various proportions of the complexes MX2+, MX| + , , MXzn+ in addition to the free metal ions. Both the free and the complexed ions can participate in the electrode reaction. Under equilibrium conditions described by Eqs (5.6.7), the following electrode reactions can occur according to H. Gerischer:

Check to ensure there are no vented tiles in the hot aisles. Increase cold aisles to two tiles wide if possible. Use unloaded racks with blanking panels between blade racks to prevent hot air from going around the sides to the intake area. Place CRACs (computer room air conditioners) perpendicular to hot aisles for maximum efficiency. Place the hottest (highest-kW) racks in the center of the row (hot aisle). If possible, move the UPS (uninterruptible power supply) outside of the room to keep out the heat. If the blade solution you are implementing uses something other than front-to-back cooling (for example, Verari Systems cools their blade solutions from bottom to top), check with that vendor for specific recommendations on the data-center layout best suited to cooling their blade systems.

4. Ability to form microphase-separated lms 5. Simple characterization of the nanostructures obtained Sidorenko et al. succeeded in fabrication of well-ordered nanostructures in thin polymer lms by supramolecular assembly of PS-b-P4VP and 2-(4-hydroxybenzeneazo) benzoic acid (HABA), consisting of cylindrical nanodomains formed by P4VP-HABA associates in a matrix of PS (Sidorenko et al., 2003). As shown in Scheme 12.7, extraction of HABA with a selective solvent results in nanochannel membranes with a hexagonal lattice of hollow channels in the diameter crossing the membrane from top to bottom. The supramolecular self-assembly between PS-b-poly(acrylic acid) (PAA) and imidazole-terminated hydrogen-bonding mesogenic groups was also used to prepare non-azo LCBCs (Chao et al., 2004). Owing to the attached LC properties, the nanostructures in the LCBC lms obtained can be oriented by using an alternating current (AC) electric eld, in a direction parallel to the electrodes.

(5.6.8)