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The application drives the business decision. Understanding your application environment, as well as your existing infrastructure, is crucial to defining and creating a successful virtualized environment. This applies to sizing of resources as well as deciding which application environments fit well together on one blade and whether some applications are best left outside the virtual environment for now. For most applications, the move to a virtual environment is trivial. However, there are a number of things to consider prior to a move. Q Are all the applications that are intended for the virtual environment mission critical If so, are there peak timeframes associated with these applications

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-,Ag + )|AgCl(Ag + ,C1")l Ag(Ag+ ,e) 1 Pt(e) (3.1.41)

Figure 12.6. POM images of PEO-based azo BCs. Illustration of the possible smectic LC layer structures is given on the left of each POM image. Source: Reproduced with modi cations from Tian et al., 2002.

The electrodes employed will be considered in greater detail in Section 3.2. Here it is sufficient that this cell can yield electrical energy, because the cell reaction ^H2(2) + AgCl(4)-> H+(3) + CT(3) + Ag(5) (3.1.42)

The amount of resources required by the multiple application environments is only part of the equation. The other part is when the resources are needed, especially with mission critical applications.

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elastomers (such as styrene-butadiene-styrene triblock copolymer). Semi uorinated alkyl substituents of the azo moieties may decrease the surface energy of azo BC lms. Moreover, it is possible for suf ciently long per uoroalkyl units to stabilize the surface so that azo photoisomerization does not change the surface properties (Paik et al., 2007). In addition, poly(2-methoxyethyl vinyl ether) [poly(MOVE)]base azo BC can supply the polymer surface with the thermally controlled water wettability because of the presence of the poly(MOVE) block (Yoshida, 2005).

takes place spontaneously. Depending on the processes occurring during the cell reaction at the individual electrodes, the cell reaction can be separated into two half-cell reactions formulated as reduction by electrons. For the cell reaction described by Eq. (3.1.42), these reactions are AgCl(4) + e = Ag(5) + Cl~(3) H (3) + e = iH2(2)

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Azo BCs are one fascinating class of soft materials, showing a rich variety of microphase-separated nanostructures in lms because the strongly bonded azo segments and the non-azo blocks are thermodynamically incompatible. As shown in Fig. 12.1, the microphase-separated morphologies can be controlled to be spheres, cylinders, or lamellae, depending on the length, chemical nature, architecture, and number of repeated units in each block (e.g., Thomas and Lescanec, 1994). When the azo block shows LC properties, the inherent mesogenic ordering might act on the thermodynamic process of microphase separation by SMCM.

Understanding resource requirements over the application execution cycle (time) will allow you to better match applications to be run concurrently within the virtual environment on a single blade. Q Do your applications rely heavily on disk accesses

(3.1.43) (3.1.44)

The investigation of azo LCBCs can undoubtedly fertilize the detailed illustration of microphase separation, and completely novel nanostructures and phase behaviors are expected by the supramolecular self-assembly. Recently, a novel wormlike nanostructure composed of azo mesogens was observed in azo LCBC lms formed by PMMA155-b-PMA(11Az)25, as shown in Fig. 12.7. Although nanoscale wormlike morphologies have been obtained in micelles formed by BC solutions (Discher and Eisenberg, 2002), they have never been reported in bulk lms. Because of the difference in elastic modulus between amorphous PMMA and the azo LC phases, wormlike microphase domains were clearly observed in atomic force microscopic (AFM) images of the LCBC lms (Yu et al., 2007b). According to the molecular component of the azo BC, the wormlike domains with a width of 25 nm should be segregated by the azo blocks, leading to the disappearance of an LC texture after microphase separation because of the limited POM resolution. The novel wormlike nanostructures might be caused by the balance between microphase separation and LC self-assembly, which makes it different from the phase-segregated morphologies of BCs with weak molecular interactions (Yu et al., 2007b).

Subtraction of reaction (3.1.44) from reaction (3.1.43) yields reaction (3.1.42). The EMF, E, is given by the difference in the inner potentials of phases V and 1: E = <t>(l')-<t>(l) (3.1.45)

Applications with heavy disk access requirements, such as some databases, may not be the best candidates for a virtual environment until the virtual I/O performance issues are addressed (see Choosing a Virtualization Architecture later in this chapter).

Figure 12.7. Wormlike microphase-separated nanostructures obtained by supramolecular self-assembly in bulk lms of a well-de ned azo LCBC. Source: Reproduced with modi cations from Yu et al., 2007b.

If this EMF is compensated by an external electrical potential difference of the same magnitude and of opposite polarity, then no current flows and the system is at equilibrium. The phase equilibria of communicating species are

fici,3 = Aci-,4; Ag+,4 = MAg+,5; Ae,l = ]Ue,5 (3.1.46)

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