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Thus the time during which the transport process attains the steady state depends strongly on the radius of the sphere r0. The steady state is connected with the dimensions of the surface to which diffusion transport takes place and does, in fact, not depend much on its shape. Diffusion to a semispherical surface located on an impermeable planar surface occurs in the same way as to a spherical surface in infinite space. The properties of diffusion to a disk-shaped surface located in an impermeable plane are not very different. The material flux is inversely proportional to the radius of the surface and the time during which stationary concentration distribution is attained decreases with the square of the disk radius. This is especially important for application of microelectrodes (see page 292). Further examples of diffusion processes characterized by boundary conditions connected with specific electrode processes will be considered in Section 5.4. 2.5.2 Simultaneous diffusion and migration

Blades tasked with parts of a computational task performing different parts of the task (running asynchronously) on each blade

The triblock copolymer was designed to have a rubbery midblock of poly(n-butyl acrylate) (PnBA) and two end blocks of poly{6-[4-(4-methoxyphenylazo)phenoxy]hexyl methacrylate} (PAzoMA) that is azo-SCLCP For synthesis, a dibromo initiator, namely, 1,1u-biphenyl-4,4u-bis(2-bromoisobutyrate), can rst be used to prepare the dibromo PnBA macroinitiator, which is then used to polymerize the azobenzene methacrylate monomer to yield the two end blocks of PAzoMA This ATE is different from azo-SCLCP-grafted SBS It is a thermoplastic elastomer, in which.

Consider a dilute electrolyte solution containing s components (nonelectrolytes and various ionic species) in which concentration gradients of the components and an electric field are present. The material flux of the ith component is then given by a combination of Eqs (2.3.11) to (2.3.20): J, = -ut(RT grad ct + c^F grad <j>) This relationship can be expressed in the form J,-=-!*, <:, grad ft (2.5.23) (2.5.22)

CH 2 )

9

Ill where the driving force for the simultaneous diffusion and migration is the gradient of the electrochemical potential /i, = jU, + z{F(^. The concept of the electrochemical potential is discussed in detail in Section 3.1.1. Equations (2.3.11), (2.3.16) and (2.3.18) can be combined to give J, = -Dt grad c, - - ^ UiCi grad 0 or, for transport with respect to coordinate x alone,

( CH 2 C )

(2.5.24)

Grid clusters (used for grid computing) are much like the other clusters described in this chapter. The primary difference is that grid clusters are made up of computers that typically have no working knowledge of other systems in the cluster. They, therefore, tend to perform work independent of the other computers in the grid with minimal data sharing. Also, the computers in a grid will often consist of heterogeneous platforms rather than the homogenous environments supported in traditional clusters. Grid clustering requires asynchronous processing in which intermediate results of one task do not affect the other tasks allocated to the other nodes on the grid. One application of grid clusters that is gaining popularity is enterprise grids (see Figure 9.4). Enterprise grids allow multiple departments within the company to share resources across an enterprise or campus. With an enterprise grid, the security and policy management issues are well contained and easier to implement.

\zt\

( CH2 )6

(2.5.25)

( CH2)6

Companies with global reach are also implementing global grids made up of collections of smaller grids and clusters within the company, sometimes referred to as departmental clusters. This is often the case in environments where work is being done 24/7, such as sales, customer support centers, and global engineering departments. As companies consolidate servers and storage, blades often become part of an enterprise grid in which computing and storage resources are shared. The modularity of blades, along with their ease of provisioning and reprovisioning, makes them an excellent platform for grid computing.

Equations (2.5.22) and (2.5.25) are called the Nernst-Planck equations. Substitution for J, from Eq. (2.5.24) into Faraday's law (2.3.14) yields the equation j = - S ZiFDt grad c, - 2 \zt\ FU& grad 0 which, combined with the conductivity relationship (2.4.2), yields j = - 2 ZiFDi grad ct - K grad </> (2.5.27) (2.5.26)

( CH2 )6

Is 2 ZiFDf grad c,

Many blade vendors offer multiple processors on each blade (often referred to as multisocket or multi-CPU configurations). If the operating system running on the blade supports SMP, such as Linux (2.0 or higher), Solaris, or Windows XP Professional, parallel applications can take advantage of SMP capabilities. Several blade vendors have implemented hypertransport technology on their blades. Implementing hypertransport on blades has enabled companies like PANTA Systems and Fujitsu Siemens to aggregate blades into SMP clusters. For example, PANTA Systems can configure, on the fly, two contiguous four-socket, dual-core blades into a single eight-socket (16 core) SMP cluster.

Figure 11.3. Two methods for the synthesis of azobenzene thermoplastic elastomers: (a) grafting of an azobenzene-containing side-chain liquid crystalline polymer (azo-SCLCP) onto the thermoplastic styrene butadiene styrene (SBS) triblock copolymer using radical polymerization, and (b) triblock copolymer composed of a rubbery central block and two azobenzene SCLCP end blocks synthesized using atom transfer radical polymerization (ATRP).

(2.5.28)