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Surface films can be studied with sufficient sensitivity in a wide range of thicknesses, starting with submonolayers Ellipsometry was also applied to the study of the electrical double layer Raman spectroscopy is certainly one of the most important optical methods employed in electrochemistry This method is based on an analysis.

Figure 11.13. Increase in diffraction ef ciency with exposure time for the second grating recorded on an ATE lm stretched to 400% strain. The inset shows the dynamic process of the rst 40 s. The period of grating is 5 mm, and the power per recording beam is 160 mW/cm2. Source: Zhao et al., 2003. Reprinted with permission.

move functions currently performed by software down onto the chip, reducing overhead and making hypervisor virtualization significantly more efficient. This has the added benefit of making the hypervisor software much less complex. An example of this is support for nested-page tables for smooth transitions between the hypervisor and virtual machine guest operating systems. Rather than the software having to manage page tables, the processor can do this more efficiently. These advancements from the chip vendors will cause a ripple in the rest of the blade and virtualization markets. Processor improvements will force memory, blade, and I/O vendors to focus on providing balanced architectures with faster I/O bandwidth. In addition, all of these vendors will have to keep an eye toward power improvements, which will also reduce cooling requirements.

336 of non-elastically scattered radiation in the ultraviolet and visible regions Interaction with vibrational states in the scattering medium leads to a slight decrease (or increase) in the frequency of the scattered radiation compared to the incident radiation As a result of specific selection rules, this method yields structural bonding data complementary to the data obtained by other vibrational spectroscopic methods, especially infrared The low intensity of the scattered light and the low shift of the frequency make it essential that the excitation radiation have very precisely defined frequency and high intensity; at present, lasers are exclusively used for this purpose When the frequency of the excitation radiation is identical with that of the electronic absorption band of the studied molecule, a marked increase in the intensity of the Raman effect is observed, exploited in Raman resonance spectroscopy.

Figure 11.14. Polarizing optical micrographs showing the grating remained in the lm 7 months after the recording. The period in the relaxed state is 1 mm, and it increases to 2.5 mm under a strain of 150%. Source: Zhao et al., 2003. Reprinted with permission.

Compared to infrared spectroscopy, the use of Raman spectroscopy in electrochemistry is favoured by the high transparence of the electrolyte in the ultraviolet and visible regions, enabling measurements in situ Compared to electronic spectra in the ultraviolet and visible regions, Raman spectra of electrochemically generated substances are characterized by high chemical selectivity and thus far greater capabilities in the study of mechanistic and kinetic problems An optical multichannel analyser can be used to study spectra with a high time resolution, ie at various stages during the change of the electrode potential A study of the adsorption of pyridine on a silver electrode first demonstrated that, under suitable conditions, Raman spectroscopy can even be sufficiently sensitive for the study of substances adsorbed on electrodes, where a modification called surface enhanced Raman spectroscopy (SERS) was used.

Blade vendors will be looking to their memory suppliers for larger amounts of memory to keep these multicore processors fed with data. The memory market, for quite a few years, has been driven only by economics, with everdecreasing costs for memory. As power and cooling (and the costs for that energy) increase, it will be interesting to see how memory vendors respond to these new demands for balanced performance per watt. Over the next few years, watch for a transition from DDR2 (Double Data Rate 2) memory to the next generation, DDR3. How that transition will take place and exactly what it will look like are not yet clear.

Dn. Within the Raman Nath regime, the grating index modulation can be estimated from ZE(pdDn/l)2 using the measured Z and the lm thickness d calculated from d = doG 0.5 at each draw ratio (initial lm thickness do=26 mm) (Zhao et al., 2003). The results show that Z changes in a reversible fashion within experimental errors, increasing slightly with the deformation up to a strain of B50% while decreasing at larger strains. At large lm deformations, the sharp decrease in Z is caused by a diminishing index modulation and the decrease in lm thickness.